Aldehydes Ketones & Carboxylic Acid
Aldehydes
- Functional Group: CHO (carbonyl group attached to a hydrogen atom)
- General Formula: RCHO (R is a hydrocarbon group)
- Examples: Formaldehyde, acetaldehyde, benzaldehyde
- Properties:
- Reactive due to the polar carbonyl group
- Undergo nucleophilic addition reactions
- Can be oxidized to carboxylic acids
- Have a characteristic odor (often pungent)
Ketones
- Functional Group: CO (carbonyl group attached to two hydrocarbon groups)
- General Formula: RCOR' (R and R' are hydrocarbon groups)
- Examples: Acetone, butanone, cyclohexanone
- Properties:
- Less reactive than aldehydes due to the steric hindrance of the two hydrocarbon groups
- Undergo nucleophilic addition reactions
- Cannot be oxidized to carboxylic acids
- Often used as solvents
Carboxylic Acids
- Functional Group: COOH (carboxyl group)
- General Formula: RCOOH (R is a hydrocarbon group)
- Examples: Acetic acid, formic acid, benzoic acid
- Properties:
- Acidic due to the presence of the carboxyl group
- Can form salts with bases
- Undergo esterification reactions
- Have a sour taste
Key Differences
Feature | Aldehydes | Ketones | Carboxylic Acids |
---|---|---|---|
Functional Group | CHO | CO | COOH |
Reactivity | More reactive | Less reactive | Acidic |
Oxidation | Oxidized to carboxylic acids | Cannot be oxidized | Do not undergo oxidation |
Examples | Formaldehyde, acetaldehyde | Acetone, butanone | Acetic acid, formic acid |
Note: These are just a few key points about aldehydes, ketones, and carboxylic acids.